A study on the effect of heating rate during cellulose and polyethylene co-pyrolysis
刘波郭欣吴棒刘子蒙
LIU Bo;GUO Xin;WU Bang;LIU Zi-meng
华中科技大学 煤燃烧国家重点实验室华中科技大学 中欧清洁与可再生能源学院
在管式炉反应器中,对纤维素(CE)与高密度聚乙烯(HDPE)进行了慢速共热解和快速共热解的研究,考察了升温速率和混合比例对CE与HDPE共热解的影响。结果表明,CE与HDPE慢速共热解可以提高液态产率,并降低气态产率和焦炭产率。在CE与HDPE比为1∶3时,慢速共热解相互作用最强烈,此时液态产率为95.4%,与计算值相比,增加了9.8%;而快速共热解降低液态产率,同时提高气态产率。在CE与HDPE比为3∶1时,快速共热解相互作用最强烈,此时液态产率与气态产率分别为49.3%和42.8%,与计算值相比,液态产率降低了14.5%,而气态产率提高了14.1%。热解油分析结果表明,CE与HDPE共热解存在协同效应,CE与HDPE共热解有利于降低液态产物的含氧量,提高焦油的质量。
Slow co-pyrolysis and fast co-pyrolysis of cellulose (CE) with high density polyethylene (HDPE) were investigated in a tube furnace reactor. The effects of heating rate and mixing ratio on the co-pyrolysis of CE and HDPE were investigated. The results show that slow co-pyrolysis of CE and HDPE can boost liquid yields while lowering gas and char yields. When the ratio of CE to HDPE is 1∶3, the slow co-pyrolysis interaction is strongest. At this ratio, the liquid yield was 95.4%. Compared with the calculated yield, the liquid yield is increased by 9.8%. Rapid co-pyrolysis reduce the liquid yield, but increase the gas yield. When the ratio of CE to HDPE is 3∶1, the rapid co-pyrolysis interaction is strongest. The liquid and gas yields were 49.3% and 42.8%, respectively. Compared with the calculated yields, the liquid yield is reduced by 14.5% but the gas yield is increased by 14.1%. These results verified that the synergistic effect existed during co-pyrolysis of CE and HDPE under the experimental conditions. Co-pyrolysis of CE and HDPE favors reducing the oxygen content of the liquid product and improving the quality of the liquid product.
共热解纤维素聚乙烯相互作用
co-pyrolysis;cellulose;polyethylene;interaction
主办单位:煤炭科学研究总院有限公司 中国煤炭学会学术期刊工作委员会