Properties of CO2 adsorption and migration during carbon sequestration in confined spaces
司小昆
SI Xiaokun
黄河交通学院交通工程学院
煤储层注CO2过程中,CO2的扩散和吸附进展缓慢,不同注气压力下吸附-运移时效特征对设计煤层封存CO2具有重要影响。因此,采用双能X射线CT扫描,并计算分析了煤储层在围压下注气前后煤心密度变化和CO2浓度。研究结果表明:在煤心的不同区域,气体以不同的速度运移,扩散和吸附进展缓慢;煤心中平均CO2浓度随时间和CO2注入压力的增加而增加,CO2浓度从注气端向出口段沿煤心轴向几乎单调下降;煤心中CO2浓度分布不均匀,煤心密度较高区域CO2浓度越低(矿物质影响),煤基质密度较小处CO2浓度越高。
During the process of injecting CO2 into coal reservoirs, the diffusion and adsorption of CO2 are slow process, and the adsorption and migration time characteristics under different injection pressures have a significant impact on the design of coal seam CO2 storage. Therefore, dual energy X-ray CT scanning was used to calculate and analyze the changes of coal core density and CO2 concentration before and after gas injection in coal reservoirs under confining pressure. The results show that in different regions of coal core, gas migrates at different speed conditions, and diffusion and adsorption progress are slow. The average CO2 concentration in the coal core increases with the increase of time and CO2 injection pressure, and the CO2 concentration almost monotonically decreases along the axial direction of coal core from gas injection end to outlet section. The distribution of CO2 concentration in coal core is uneven. The lower the CO2 concentration in areas with high core density (mineral influence) is, the higher the CO2 concentration in areas with low coal matrix density is.
CO2吸附煤储层CO2封存CO2运移注气压力围压CT扫描
CO2 adsorption;coal reservoirs;CO2 storage;CO2 migration;gas injection pressure;confining pressure;CT scan
主办单位:煤炭科学研究总院有限公司 中国煤炭学会学术期刊工作委员会